The Suzuki-Miyaura reaction after the Nobel prize

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Title: The Suzuki-Miyaura reaction after the Nobel prize
Authors: Beletskaya, Irina P. | Alonso, Francisco | Tyurin, Vladimir
Research Group/s: Nuevos Materiales y Catalizadores (MATCAT)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica
Keywords: Synthetic organic chemistry | Suzuki-Miyaura reaction
Knowledge Area: Química Orgánica
Issue Date: 15-Apr-2019
Publisher: Elsevier
Citation: Coordination Chemistry Reviews. 2019, 385: 137-173. doi:10.1016/j.ccr.2019.01.012
Abstract: Synthetic organic chemistry experienced a significant advance in the last quarter of the 20th century with the advent of the transition-metal catalyzed cross-coupling reactions. The utility of these reactions was universally acknowledged and expressed in the Chemistry Nobel prize awarded to professors Heck, Suzuki and Negishi in 2010. In this scenario, the discovery of the Suzuki-Miyaura reaction was a landmark that occupies a privileged position because of its versatility, compatibility and pivotal contribution to diverse disciplines, including materials science and drug discovery. Despite the substantial progress attained for this reaction until 2010, there is still room for improvement, particularly, if we are concerned about the health of the Earth and aware of the paramount importance to produce substances under the guidelines of sustainable and Green Chemistry. In the present review, we summarize the efforts devoted by a wide and specialized scientific community to upgrade the Suzuki-Miyaura reaction during the post-Nobel prize period. An overview covering new catalytic systems, methods and conditions is provided, together with some applications and updated mechanistic viewpoints.
Sponsor: Francisco Alonso gratefully acknowledges the Spanish Ministerio de Economía y Competitividad (MINECO; grant no. CTQ2017-88171-P) and the Generalitat Valenciana (GV; grant no. AICO/2017/007) for financial support.
ISSN: 0010-8545 (Print) | 1873-3840 (Online)
DOI: 10.1016/j.ccr.2019.01.012
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2019 Published by Elsevier B.V.
Peer Review: si
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Appears in Collections:INV - MATCAT - Artículos de Revistas

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