Fabrication of Co/P25 coated with thin nitrogen-doped carbon shells (Co/P25/NC) as an efficient electrocatalyst for oxygen reduction reaction (ORR)
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http://hdl.handle.net/10045/86948
Títol: | Fabrication of Co/P25 coated with thin nitrogen-doped carbon shells (Co/P25/NC) as an efficient electrocatalyst for oxygen reduction reaction (ORR) |
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Autors: | Miyake, Koji | Takemura, Toshiki | Gabe, Atsushi | Zhu, Yexin | Ota, Misaki | Shu, Yasuhiro | Hirota, Yuichiro | Uchida, Yoshiaki | Tanaka, Shunsuke | Katayama, Misaki | Inada, Yasuhiro | Morallon, Emilia | Cazorla-Amorós, Diego | Nishiyama, Norikazu |
Grups d'investigació o GITE: | Electrocatálisis y Electroquímica de Polímeros | Materiales Carbonosos y Medio Ambiente |
Centre, Departament o Servei: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales |
Paraules clau: | P25 | Core-shell | CVD | CoNx | ORR |
Àrees de coneixement: | Química Física | Química Inorgánica |
Data de publicació: | 10-de febrer-2019 |
Editor: | Elsevier |
Citació bibliogràfica: | Electrochimica Acta. 2019, 296: 867-873. doi:10.1016/j.electacta.2018.11.080 |
Resum: | Development of electrocatalysts for oxygen reduction reaction (ORR) is important to solve the current problems about energy and fuel. As one of the catalysts with high performance, platina group metals (PGM) based catalysts have been widely known. However, PGM based catalysts are not suitable for large commercial application since the PGM based catalysts are so expensive. In this work, we have developed TiO2 P25 coated with Co and nitrogen-doped carbon layers using commercially available and inexpensive P25 as a support (Co/P25/NC) as one of the alternatives to PGM based catalysts. Co/P25/NC showed an excellent catalytic activity on ORR compared to the other catalysts prepared using SiO2, ZrO2 and Al2O3 as a support. The ORR activity of Co/P25/NC was comparable to Pt based electrocatalysts. In addition, Co/P25/NC showed excellent durability and tolerance toward methanol compared to the Pt based catalyst. This work would provide a new synthetic strategy of electrocatalysts. |
Patrocinadors: | The financial support by MINECO, Spain (CTQ2015-66080-R (MINECO/FEDER)) and HEIWA NAKAJIMA FOUNDATION is acknowledged. |
URI: | http://hdl.handle.net/10045/86948 |
ISSN: | 0013-4686 (Print) | 1873-3859 (Online) |
DOI: | 10.1016/j.electacta.2018.11.080 |
Idioma: | eng |
Tipus: | info:eu-repo/semantics/article |
Drets: | © 2018 Elsevier Ltd. |
Revisió científica: | si |
Versió de l'editor: | https://doi.org/10.1016/j.electacta.2018.11.080 |
Apareix a la col·lecció: | INV - MCMA - Artículos de Revistas INV - GEPE - Artículos de Revistas |
Arxius per aquest ítem:
Arxiu | Descripció | Tamany | Format | |
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2019_Miyake_etal_ElectrActa_final.pdf | Versión final (acceso restringido) | 2,02 MB | Adobe PDF | Obrir Sol·licitar una còpia |
2019_Miyake_etal_ElectrActa_accepted.pdf | Accepted Manuscript (acceso abierto) | 4,64 MB | Adobe PDF | Obrir Vista prèvia |
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