Understanding the promoter effect of Cu and Cs over highly effective β-Mo2C catalysts for the reverse water-gas shift reaction

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/86219
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dc.contributorMateriales Avanzadoses_ES
dc.contributor.authorZhang, Q.-
dc.contributor.authorPastor Pérez, Laura-
dc.contributor.authorJin, Wei-
dc.contributor.authorGu, Sai-
dc.contributor.authorRamírez Reina, Tomás-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Inorgánicaes_ES
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Materialeses_ES
dc.date.accessioned2019-01-17T15:47:44Z-
dc.date.available2019-01-17T15:47:44Z-
dc.date.issued2019-05-05-
dc.identifier.citationApplied Catalysis B: Environmental. 2019, 244: 889-898. doi:10.1016/j.apcatb.2018.12.023es_ES
dc.identifier.issn0926-3373 (Print)-
dc.identifier.issn1873-3883 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/86219-
dc.description.abstractMo2C is an effective catalyst for chemical CO2 upgrading via reverse water-gas shift (RWGS). In this work, we demonstrate that the activity and selectivity of this system can be boosted by the addition of promoters such as Cu and Cs. The addition of Cu incorporates extra active sites such as Cu+ and Cu° which are essential for the reaction. Cs is an underexplored dopant whose marked electropositive character generates electronic perturbations on the catalyst’s surface leading to enhanced catalytic performance. Also, the Cs-doped catalyst seems to be in-situ activated due to a re-carburization phenomenon which results in fairly stable catalysts for continuous operations. Overall, this work showcases a strategy to design highly efficient catalysts based on promoted β-Mo2C for CO2 recycling via RWGS.es_ES
dc.description.sponsorshipFinancial support for this work was provided by the Department of Chemical and Process Engineering at the University of Surrey and the EPSRC grant EP/R512904/1 as well as the Royal Society Research GrantRSGR1180353. LPP acknowledge Comunitat Valenciana for her APOSTD2017 fellowship. This work was also partially sponsored by the CO2Chem through the EPSRC grant EP/P026435/1.es_ES
dc.languageenges_ES
dc.publisherElsevieres_ES
dc.rights© 2018 Published by Elsevier B.V. Under a Creative Commons Attribution 4.0 International licensees_ES
dc.subjectCO2conversiones_ES
dc.subjectrWGSes_ES
dc.subjectMo2C catalystes_ES
dc.subjectCs promoteres_ES
dc.subjectCu promoteres_ES
dc.subject.otherQuímica Inorgánicaes_ES
dc.titleUnderstanding the promoter effect of Cu and Cs over highly effective β-Mo2C catalysts for the reverse water-gas shift reactiones_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.peerreviewedsies_ES
dc.identifier.doi10.1016/j.apcatb.2018.12.023-
dc.relation.publisherversionhttps://doi.org/10.1016/j.apcatb.2018.12.023es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
Appears in Collections:INV - LMA - Artículos de Revistas

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