Mechanistic aspects of glycerol electrooxidation on Pt(111) electrode in alkaline media

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Title: Mechanistic aspects of glycerol electrooxidation on Pt(111) electrode in alkaline media
Authors: Sandrini, Regiani M.L.M. | Sempionatto, Juliane Renata | Herrero, Enrique | Feliu, Juan M. | Souza-Garcia, Janaina | Angelucci, Camilo Andrea
Research Group/s: Electroquímica de Superficies
Center, Department or Service: Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica
Keywords: Glycerol | Pt(111) | Electro-oxidation | In situ FTIR | Alkaline media
Knowledge Area: Química Física
Issue Date: Jan-2018
Publisher: Elsevier
Citation: Electrochemistry Communications. 2018, 86: 149-152. doi:10.1016/j.elecom.2017.11.027
Abstract: Glycerol electrooxidation reaction (GEOR) in alkaline media was studied on the Pt(111) electrode with in situ FTIR and electrochemical methods. Cyclic voltammogram profiles display strong electrode deactivation after the first potential scan. Chronoamperometric pulses demonstrate that the deactivation is a result of the reaction intermediates yielded during the faradaic process. In situ FTIR shows evidence that the strongly adsorbed intermediate formed during GEOR is an acyl species which remains present on the surface within the potential window studied.
Sponsor: This work was supported by CNPq (projects 474590/2013-5 and 456758/2014-3), FAPESP (project 2013/13749-0) and Capes for the financial support.
URI: http://hdl.handle.net/10045/82447
ISSN: 1388-2481 (Print) | 1873-1902 (Online)
DOI: 10.1016/j.elecom.2017.11.027
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2017 Elsevier B.V.
Peer Review: si
Publisher version: https://doi.org/10.1016/j.elecom.2017.11.027
Appears in Collections:INV - EQSUP - Artículos de Revistas

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