Triphenyl(3-sulfopropyl)phosphonium trinitromethanide as a novel nanosized molten salt: Catalytic activity at the preparation of dihydropyrano[2,3-c]pyrazoles

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Title: Triphenyl(3-sulfopropyl)phosphonium trinitromethanide as a novel nanosized molten salt: Catalytic activity at the preparation of dihydropyrano[2,3-c]pyrazoles
Authors: Yarie, Meysam | Zolfigol, Mohammad Ali | Baghery, Saeed | Alonso, Diego A. | Khoshnood, Abbas | Bayat, Yadollah | Asgari, Asiye
Research Group/s: Catálisis Estereoselectiva en Síntesis Orgánica (CESO)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica
Keywords: Triphenyl(3-sulfopropyl)phosphonium trinitromethanide | Nanosized molten salt | Pyrano[3,2-c]pyrazole derivatives | Multicomponent reactions
Knowledge Area: Química Orgánica
Issue Date: 1-Dec-2018
Publisher: Elsevier
Citation: Journal of Molecular Liquids. 2018, 271: 872-884. doi:10.1016/j.molliq.2018.09.054
Abstract: In this paper, designing, preparation and characterization of a unique nanosized molten salt namely triphenyl(3-sulfopropyl)phosphonium trinitromethanide (TPSPPTNM) was reported. The successful formation of nanosized catalyst was verified by using suitable skills like fourier transform infrared spectroscopy (FT-IR), proton, carbon and phosphor NMR, X-ray diffraction patterns (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray analysis (EDX), SEM elemental mapping, high resolution transmission electron microscopy (HRTEM), thermogravimetry (TG) and derivative thermogravimetry (DTG) analysis. The catalytic application of the novel molten salt was explored towards the synthesis of pyrano[3,2-c]pyrazole derivatives under mild and green reaction conditions.
Sponsor: We thank Bu-Ali Sina University, Iran National Science Foundation (INSF) (Grant Number: 940124), National Elites Foundation, University of Alicante (VIGROB-173, UAUSTI16-03), and the Spanish Ministerio de Economía y Competitividad (CTQ2015-66624-P) for financial support to our research groups.
URI: http://hdl.handle.net/10045/80487
ISSN: 0167-7322 (Print) | 1873-3166 (Online)
DOI: 10.1016/j.molliq.2018.09.054
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2018 Published by Elsevier B.V.
Peer Review: si
Publisher version: https://doi.org/10.1016/j.molliq.2018.09.054
Appears in Collections:INV - CESO - Artículos de Revistas

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