Chemical and electrochemical characterization of porous carbon materials

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/7765
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dc.contributorElectrocatálisis y Electroquímica de Polímerosen
dc.contributor.authorBleda Martínez, María Jesús-
dc.contributor.authorLozano Castelló, Dolores-
dc.contributor.authorMorallon, Emilia-
dc.contributor.authorCazorla-Amorós, Diego-
dc.contributor.authorLinares-Solano, Angel-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Inorgánicaen
dc.contributor.otherUniversidad de Alicante. Departamento de Química Físicaen
dc.date.accessioned2008-09-22T10:26:19Z-
dc.date.available2008-09-22T10:26:19Z-
dc.date.created2006-04-11-
dc.date.issued2006-05-19-
dc.identifier.citationBLEDA MARTÍNEZ, María Jesús, et al. "Chemical and electrochemical characterization of porous carbon materials". Carbon. Vol. 44, Issue 13 (Nov. 2006). ISSN 0008-6223, pp. 2642-2651en
dc.identifier.issn0008-6223-
dc.identifier.urihttp://hdl.handle.net/10045/7765-
dc.description.abstractChemical and electrochemical techniques have been used in order to asses surface functionalities of porous carbon materials. An anthracite has been chemically activated using both KOH and NaOH as activating agents. As a result, activated carbons with high micropore volume (higher than 1 cm3/g) have been obtained. These samples were oxidized with HNO3 and thermally treated in N2 flow at different temperatures in order to obtain porous carbon materials with different amounts of surface oxygen complexes. Thermal treatment in H2 was also carried out. The sample treated with H2 was subsequently treated in air flow at 450 ºC. Thus, materials with very similar porous texture and widely different surface chemistry have been compared. The surface chemistry of the resulting materials was systematically characterized by TPD experiments and XPS measurements. Galvanostatic and voltammetric techniques were used to deepen into the characterization of the surface oxygen complexes. The combination of both, chemical and electrochemical methods provide unique information, regarding the key role of surface chemistry in improving carbon wettability in aqueous solution and the redox processes undergone by the surface oxygen groups. Both contributions are of relevance to understand the use of porous carbons as electrochemical capacitors.en
dc.description.sponsorshipMinisterio de Ciencia y Tecnología (PPQ2003-03884).en
dc.languageengen
dc.publisherElsevieren
dc.subjectActivated carbonen
dc.subjectChemical treatmenten
dc.subjectTemperature programmed desorptionen
dc.subjectElectrochemical propertiesen
dc.subjectSurface oxigen complexesen
dc.subject.otherQuímica Físicaen
dc.subject.otherCiencia de Materialesen
dc.titleChemical and electrochemical characterization of porous carbon materialsen
dc.typeinfo:eu-repo/semantics/articleen
dc.peerreviewedsien
dc.identifier.doi10.1016/j.carbon.2006.04.017-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.carbon.2006.04.017-
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccess-
Appears in Collections:INV - GEPE - Artículos de Revistas

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