Synthesis of a Biological‐Based Glycoluril with Phosphorous Acid Tags as a New Nanostructured Catalyst: Application for the Synthesis of Novel Natural Henna‐Based Compounds
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Título: | Synthesis of a Biological‐Based Glycoluril with Phosphorous Acid Tags as a New Nanostructured Catalyst: Application for the Synthesis of Novel Natural Henna‐Based Compounds |
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Autor/es: | Moradi, Saeid | Zolfigol, Mohammad Ali | Zarei, Mahmoud | Alonso, Diego A. | Khoshnood, Abbas |
Grupo/s de investigación o GITE: | Catálisis Estereoselectiva en Síntesis Orgánica (CESO) |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica |
Palabras clave: | Glycoluril | Glycoluril tetrakis(methylene phosphorous acid) (GTMPA) | Biological-based | Nanostructured catalyst | Recyclable catalyst | 3-Methyl-1,4-diphenyl-1,4-dihydrobenzo[6,7]chromeno[2, 3-c]pyrazole-5,10-dione |
Área/s de conocimiento: | Química Orgánica |
Fecha de publicación: | 22-mar-2018 |
Editor: | Wiley-VCH Verlag GmbH & Co. KGaA |
Cita bibliográfica: | ChemistrySelect. 2018, 3(11): 3042-3047. doi:10.1002/slct.201702544 |
Resumen: | A convenient multicomponent reaction towards the synthesis of natural henna‐based 3‐methyl‐1,4‐diphenyl‐1,4‐dihydrobenzo[6, 7]chromeno[2, 3‐c]pyrazole‐5,10‐dione derivatives by using a crabby nano glycoluril tetrakis(methylene phosphorous acid) (GTMPA), as an efficient and recyclable catalyst, under neat conditions is described. The major advantages of the synthetic methodology herein described are high yields, short reaction times, and the reusability of the catalyst, which has been fully characterized by Fourier Transform Infrared Spectroscopy (FT‐IR), Solid Phosphorus Nuclear Magnetic Resonance (31P NMR), Mass spectra (MS), X‐Ray Diffraction (XRD), High Resolution Transmission Electron Microscopy (HRTEM), Scanning Electron Microscope (SEM‐Mapp.), Energy Dispersive X‐Ray (EDX), Thermo Gravimetric Analysis (TGA), Differential Thermal Analysis (DTG), Differential Thermal Analysis (DTA) and X‐Ray Photoelectron Spectroscopy (XPS). The described biological‐based glycoluril with phosphorous acid pending may be applicable for the synthesis of gels, gelators, self‐healing and smart hydrogels. |
Patrocinador/es: | We thank Bu-Ali Sina University, Iran National Science Foundation (INSF) (Grant Number: 96003376), National Elites Foundation, University of Alicante (VIGROB-173, UAUSTI16-03), and the Spanish Ministerio de Economía y Competitividad (CTQ2015-66624-P) for financial support to our research groups. |
URI: | http://hdl.handle.net/10045/74639 |
ISSN: | 2365-6549 |
DOI: | 10.1002/slct.201702544 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1002/slct.201702544 |
Aparece en las colecciones: | INV - CESO - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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2018_Moradi_etal_ChemistrySelect_final.pdf | Versión final (acceso restringido) | 4,66 MB | Adobe PDF | Abrir Solicitar una copia |
2018_Moradi_etal_ChemistrySelect_preprint.pdf | Preprint (acceso abierto) | 2,18 MB | Adobe PDF | Abrir Vista previa |
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