Plasma-Assisted Synthesis of Monodispersed and Robust Ruthenium Ultrafine Nanocatalysts for Organosilane Oxidation and Oxygen Evolution Reactions

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Title: Plasma-Assisted Synthesis of Monodispersed and Robust Ruthenium Ultrafine Nanocatalysts for Organosilane Oxidation and Oxygen Evolution Reactions
Authors: Gnanakumar, Edwin S. | Ng, Wesley | Filiz, Bilge Coşkuner | Rothenberg, Gadi | Wang, Sheng | Xu, Hualong | Pastor Pérez, Laura | Pastor-Blas, M. Mercedes | Sepúlveda-Escribano, Antonio | Yan, Ning | Shiju, N. Raveendran
Research Group/s: Materiales Avanzados
Center, Department or Service: Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Nanostructures | Oxidation | Plasma chemistry | Ruthenium | Supported catalysts
Knowledge Area: Química Inorgánica
Issue Date: 12-Oct-2017
Publisher: Wiley-VCH Verlag GmbH & Co. KGaA
Citation: ChemCatChem. 2017, 9(22): 4159-4163. doi:10.1002/cctc.201700809
Abstract: We report a facile and general approach for preparing ultrafine ruthenium nanocatalysts by using a plasma-assisted synthesis at <100 °C. The resulting Ru nanoparticles are monodispersed (typical size 2 nm) and remain that way upon loading onto carbon and TiO2 supports. This gives robust catalysts with excellent activities in both organosilane oxidation and the oxygen evolution reaction.
Sponsor: N.R.S. and E.S.G. acknowledge financial support from the NOW CAPITA project (732.013.002). A.S.E. acknowledges financial support from Generalitat Valenciana, Spain (Project PROMETEOII/2014/004). This work is part of the Research Priority Area Sustainable Chemistry of the University of Amsterdam, http://suschem.uva.nl
URI: http://hdl.handle.net/10045/70269
ISSN: 1867-3880 (Print) | 1867-3899 (Online)
DOI: 10.1002/cctc.201700809
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
Peer Review: si
Publisher version: http://dx.doi.org/10.1002/cctc.201700809
Appears in Collections:INV - LMA - Artículos de Revistas

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