Metal–organic and covalent organic frameworks as single-site catalysts

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Title: Metal–organic and covalent organic frameworks as single-site catalysts
Authors: Rogge, Sven M.J. | Bavykina, Anastasiya | Hajek, Julianna | Garcia, Hermenegildo | Olivos-Suarez, Alma I. | Sepúlveda-Escribano, Antonio | Vimont, Alexandre | Clet, Guillaume | Bazin, Philippe | Kapteijn, Freek | Daturi, Marco | Ramos-Fernández, Enrique V. | Llabrés i Xamena, Francesc X. | Van Speybroeck, Veronique | Gascon, Jorge
Research Group/s: Materiales Avanzados
Center, Department or Service: Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Single-site catalysts | Metal–organic frameworks (MOFs) | Covalent organic frameworks (COFs)
Knowledge Area: Química Inorgánica
Issue Date: 7-Jun-2017
Publisher: Royal Society of Chemistry
Citation: Chemical Society Reviews. 2017, 46: 3134-3184. doi:10.1039/C7CS00033B
Abstract: Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.
Sponsor: S. M. J. Rogge, J. Hajek, and V. Van Speybroeck acknowledge the Fund for Scientific Research – Flanders (FWO), the Research Board of Ghent University (BOF) and BELSPO in the frame of IAP/7/05 for financial support. V. Van Speybroeck acknowledges funding from the European Union’s Horizon 2020 research and innovation programme (consolidator ERC grant agreement no. 647755 – DYNPOR (2015–2020)). This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement no. 641887 (project acronym: DEFNET). W. Dewitte and C. Caratelli are acknowledged for technical support with the figures. J. Gascon acknowledges funding from the European Union’s 2020 research and innovation programme (ERC grant agreement no. 335746 – CrystEng-MOF-MMM) and from the Dutch Organization for Scientific Research (NWO, VIDI grant agreement 723.012.107 – MetMOFCat).
URI: http://hdl.handle.net/10045/66731
ISSN: 0306-0012 (Print) | 1460-4744 (Online)
DOI: 10.1039/C7CS00033B
Language: eng
Type: info:eu-repo/semantics/article
Rights: This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Peer Review: si
Publisher version: http://dx.doi.org/10.1039/C7CS00033B
Appears in Collections:INV - LMA - Artículos de Revistas
Research funded by the EU

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