Fully Automatic In-Syringe Magnetic Stirring-Assisted Dispersive Liquid–Liquid Microextraction Hyphenated to High-Temperature Torch Integrated Sample Introduction System-Inductively Coupled Plasma Spectrometer with Direct Injection of the Organic Phase

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Título: Fully Automatic In-Syringe Magnetic Stirring-Assisted Dispersive Liquid–Liquid Microextraction Hyphenated to High-Temperature Torch Integrated Sample Introduction System-Inductively Coupled Plasma Spectrometer with Direct Injection of the Organic Phase
Autor/es: Sánchez, Raquel | Horstkotte, Burkhard | Fikarová, Kateřina | Sklenářová, Hana | Maestre, Salvador E. | Miró, Manuel | Todolí Torró, José Luis
Grupo/s de investigación o GITE: Análisis de Polímeros y Nanomateriales | Análisis de Alimentos y Nutrición
Centro, Departamento o Servicio: Universidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatología
Palabras clave: Dispersive liquid–liquid microextraction | Inductively coupled plasma optical emission spectrometry | In-syringe | Magnetic stirring
Área/s de conocimiento: Química Analítica | Nutrición y Bromatología
Fecha de publicación: 23-feb-2017
Editor: American Chemical Society
Cita bibliográfica: Analytical Chemistry. 2017, 89(6): 3787-3794. doi:10.1021/acs.analchem.7b00400
Resumen: A proof of concept study involving the online coupling of automatic dispersive liquid–liquid microextraction (DLLME) to inductively coupled plasma optical emission spectrometry (ICP OES) with direct introduction and analysis of the organic extract is herein reported for the first time. The flow-based analyzer features a lab-in-syringe (LIS) setup with an integrated stirring system, a Meinhard nebulizer in combination with a heated single-pass spray chamber, and a rotary injection valve, used as an online interface between the microextraction system and the detection instrument. Air-segmented flow was used for delivery of a fraction of the nonwater miscible extraction phase, 12 μL of xylene, to the nebulizer. All sample preparative steps including magnetic stirring assisted DLLME were carried out inside the syringe void volume as a size-adaptable yet sealed mixing and extraction chamber. Determination of trace level concentrations of cadmium, copper, lead, and silver as model analytes has been demonstrated by microextraction as diethyldithiophosphate (DDTP) complexes. The automatic LIS-DLLME method features quantitative metal extraction, even in troublesome sample matrixes, such as seawater, salt, and fruit juices, with relative recoveries within the range of 94–103%, 93–100%, and 92–99%, respectively. Furthermore, no statistically significant differences at the 0.05 significance level were found between concentration values experimentally obtained and the certified values of two serum standard reference materials.
Patrocinador/es: B. Horstkotte acknowledges the financial support by an ERASMUS+ Scholarship No. XIII/3/15-16 and by the Czech Science Foundation (Project No. P206/15/10781S). K. Fikarová is thankful for an Erasmus student scholarship and financial support of the Charles University (Project SVV 260 412/2016). M. Miró acknowledges financial support from the Spanish State Research Agency through Projects CTM2014-56628-C3-3-R (AEI/FEDER, UE) and CTM2014-61553-EXP (AEI/FEDER, UE).
URI: http://hdl.handle.net/10045/66415
ISSN: 0003-2700 (Print) | 1520-6882 (Online)
DOI: 10.1021/acs.analchem.7b00400
Idioma: eng
Tipo: info:eu-repo/semantics/article
Derechos: © 2017 American Chemical Society
Revisión científica: si
Versión del editor: http://dx.doi.org/10.1021/acs.analchem.7b00400
Aparece en las colecciones:INV - APN - Artículos de Revistas
INV - Análisis de Alimentos - Artículos de Revistas

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