The Role of Adsorption in the Electrocatalysis of Hydrazine on Platinum Electrodes
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Campo DC | Valor | Idioma |
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dc.contributor | Electroquímica de Superficies | es_ES |
dc.contributor.author | Gisbert, Rubén | - |
dc.contributor.author | Boronat-González, Ana | - |
dc.contributor.author | Feliu, Juan M. | - |
dc.contributor.author | Herrero, Enrique | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Física | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Electroquímica | es_ES |
dc.date.accessioned | 2017-05-24T09:39:56Z | - |
dc.date.available | 2017-05-24T09:39:56Z | - |
dc.date.issued | 2017-05 | - |
dc.identifier.citation | ChemElectroChem. 2017, 4(5): 1130-1134. doi:10.1002/celc.201600901 | es_ES |
dc.identifier.issn | 2196-0216 | - |
dc.identifier.uri | http://hdl.handle.net/10045/66231 | - |
dc.description.abstract | Hydrazine oxidation on platinum single-crystal electrodes has been studied in acidic solution containing different electrolytes. It will be shown that the hydrazinium cation is adsorbed on platinum through an anodic reaction. Moreover, in the presence of chloride, this adsorption process is favored owing to the formation of an ionic pair with adsorbed chloride. In spite of the enhanced adsorption of hydrazine species in the presence of chloride, higher overpotentials are measured in these media, which reveals that the oxidation of hydrazine not only requires adsorption, but also that the adsorption mode of the species facilitates the formation of the transition state to yield the final product. | es_ES |
dc.description.sponsorship | This work has been financially supported by the MINECO (Spain) and Generalitat Valenciana through projects CTQ2016-76221-P and PROMETEOII/2014/013, respectively. | es_ES |
dc.language | eng | es_ES |
dc.publisher | Wiley-VCH Verlag GmbH & Co. KGaA | es_ES |
dc.rights | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | es_ES |
dc.subject | Anion adsorption effects | es_ES |
dc.subject | Co-adsorption phenomena | es_ES |
dc.subject | Hydrazine oxidation | es_ES |
dc.subject | Platinum | es_ES |
dc.subject | Single-crystal electrodes | es_ES |
dc.subject.other | Química Física | es_ES |
dc.title | The Role of Adsorption in the Electrocatalysis of Hydrazine on Platinum Electrodes | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1002/celc.201600901 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1002/celc.201600901 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-76221-P | - |
Aparece en las colecciones: | INV - EQSUP - Artículos de Revistas |
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Archivo | Descripción | Tamaño | Formato | |
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2017_Gisbert_etal_ChemElectroChem_final.pdf | Versión final (acceso restringido) | 3,04 MB | Adobe PDF | Abrir Solicitar una copia |
2017_Gisbert_etal_ChemElectroChem_accepted.pdf | Accepted Manuscript (acceso abierto) | 1,46 MB | Adobe PDF | Abrir Vista previa |
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