Hierarchical Zeolites and their Catalytic Performance in Selective Oxidative Processes

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/60255
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dc.contributorLaboratorio de Nanotecnología Molecular (NANOMOL)es_ES
dc.contributor.authorOjeda, Manuel-
dc.contributor.authorGrau-Atienza, Aida-
dc.contributor.authorCampos, Rafael-
dc.contributor.authorRomero, Antonio A.-
dc.contributor.authorSerrano, Elena-
dc.contributor.authorMarinas, Jose Maria-
dc.contributor.authorGarcia-Martinez, Javier-
dc.contributor.authorLuque, Rafael-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Inorgánicaes_ES
dc.identifier.citationChemSusChem. 2015, 8(8): 1328-1333. doi:10.1002/cssc.201500124es_ES
dc.identifier.issn1864-5631 (Print)-
dc.identifier.issn1864-564X (Online)-
dc.description.abstractHierarchical ZSM-5 zeolites prepared using a simple alkali treatment and subsequent HCl washing are found to exhibit unprecedented catalytic activities in selective oxidation of benzyl alcohol under microwave irradiation. The metal-free zeolites promote the microwave-assisted oxidation of benzyl alcohol with hydrogen peroxide in yields ranging from 45–35 % after 5 min of reaction under mild reaction conditions as well as the epoxidation of cyclohexene to valuable products (40–60 % conversion). The hierarchically porous systems also exhibited an interesting catalytic activity in the dehydration of N,N-dimethylformamide (25–30 % conversion), representing the first example of transition-metal free catalysts in this reaction.es_ES
dc.description.sponsorshipR.L. gratefully acknowledge support from the Spanish MICINN via the concession of a RyC contract (RYC 2009-04199) and funding under projects P10-FQM-6711 (Consejeria de Ciencia e Innovacion, Junta de Andalucia) and CTQ2011 28954-C02-02 (MICINN). J.G.M. gratefully aknowledges funding under project PCIN-2013-164 (MINECO and UE). Both R.L. and J.G.M. acknowledge support from MICINN under cooperation project CTQ2011-28954.es_ES
dc.publisherWiley-VCH Verlag GmbH & Co. KGaAes_ES
dc.rights© 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimes_ES
dc.subjectMesoporous materialses_ES
dc.subject.otherQuímica Inorgánicaes_ES
dc.titleHierarchical Zeolites and their Catalytic Performance in Selective Oxidative Processeses_ES
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