Multicomponent NiSnCeO2/C catalysts for the low-temperature glycerol steam reforming
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Campo DC | Valor | Idioma |
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dc.contributor | Materiales Avanzados | es_ES |
dc.contributor.author | Pastor Pérez, Laura | - |
dc.contributor.author | Sepúlveda-Escribano, Antonio | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Inorgánica | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Materiales | es_ES |
dc.date.accessioned | 2016-10-31T10:53:18Z | - |
dc.date.available | 2016-10-31T10:53:18Z | - |
dc.date.issued | 2017-01-05 | - |
dc.identifier.citation | Applied Catalysis A: General. 2017, 529: 118-126. doi:10.1016/j.apcata.2016.10.022 | es_ES |
dc.identifier.issn | 0926-860X (Print) | - |
dc.identifier.issn | 1873-3875 (Online) | - |
dc.identifier.uri | http://hdl.handle.net/10045/59431 | - |
dc.description.abstract | In this work, the low-temperature hydrogen production via glycerol steam reforming over activated carbon-supported Ni and Ni-Sn catalysts promoted by ceria was studied. A combination of N2 adsorption, powder X-ray diffraction, temperature-programmed reduction with H2, X-ray photoelectron spectroscopy and TEM analysis were used to characterise the Ni-Sn-CeO2 interactions and the CeO2 dispersion over the activated carbon support. The catalytic activity results show that the presence of ceria enhances the water-gas shift reaction, thus promoting the selectivity towards hydrogen. The inclusion of Sn stresses the influence of ceria in the displayed performance. Moreover, the formation of a Ni-Sn alloy seems to be an efficient way to mitigate Ni sintering and therefore to improve the overall catalyst’s stability. | es_ES |
dc.description.sponsorship | This work has been supported by Ministerio de Economía y Competitividad (Spain, project MAT2013-45008-P). L. P-P. acknowledges her grant BES-2011-0406508. | es_ES |
dc.language | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.rights | © 2016 Elsevier B.V. | es_ES |
dc.subject | H2 production | es_ES |
dc.subject | Nickel-tin | es_ES |
dc.subject | Glycerol | es_ES |
dc.subject | Ceria | es_ES |
dc.subject | Activated carbon | es_ES |
dc.subject.other | Química Inorgánica | es_ES |
dc.title | Multicomponent NiSnCeO2/C catalysts for the low-temperature glycerol steam reforming | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1016/j.apcata.2016.10.022 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.apcata.2016.10.022 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es_ES |
Aparece en las colecciones: | INV - LMA - Artículos de Revistas |
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Archivo | Descripción | Tamaño | Formato | |
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2017_Pastor_Sepulveda_ApplCatA_final.pdf | Versión final (acceso restringido) | 1,46 MB | Adobe PDF | Abrir Solicitar una copia |
2017_Pastor_Sepulveda_ApplCatA_accepted.pdf | Accepted Manuscript (acceso abierto) | 1,04 MB | Adobe PDF | Abrir Vista previa |
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