Recent Advances in the Direct Nucleophilic Substitution of Allylic Alcohols through SN1-Type Reactions

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Title: Recent Advances in the Direct Nucleophilic Substitution of Allylic Alcohols through SN1-Type Reactions
Authors: Baeza, Alejandro | Nájera, Carmen
Research Group/s: Nuevos Materiales y Catalizadores (MATCAT) | Síntesis Asimétrica (SINTAS)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica
Keywords: SN1 reaction | Allylic substitution | Carbocations | Allylic alcohols | Green chemistry
Knowledge Area: Química Orgánica
Issue Date: 2014
Publisher: Georg Thieme Verlag
Citation: Synthesis. 2014, 46(01): 25-34. doi:10.1055/s-0033-1340316
Abstract: Direct nucleophilic substitution reactions of allylic alcohols are environmentally friendly, since they generate only water as a byproduct, allowing access to new allylic compounds. This reaction has, thus, attracted the interest of the chemical community and several strategies have been developed for its successful accomplishment. This review gathers the latest advances in this methodology involving SN1-type reactions.
Sponsor: Spanish Ministerio de Ciencia e Innovación (MICINN) (projects CTQ2010-20387 and Consolider Ingenio 2010, CSD2007-00006), FEDER, the Generalitat Valenciana (PROMETEO 2009/039) and the University of Alicante are gratefully acknowledged for financial support. A.B. would also like to thank MICINN for a Juan de la Cierva contract (JCI-2009-03710) and the University of Alicante (Project GRE12-03).
URI: http://hdl.handle.net/10045/58135
ISSN: 0039-7881 (Print) | 1437-210X (Online)
DOI: 10.1055/s-0033-1340316
Language: eng
Type: info:eu-repo/semantics/article
Rights: © Georg Thieme Verlag Stuttgart · New York
Peer Review: si
Publisher version: http://dx.doi.org/10.1055/s-0033-1340316
Appears in Collections:INV - MATCAT - Artículos de Revistas
INV - SINTAS - Artículos de Revistas
INV - AMIC - Artículos de Revistas

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