CO2 Adsorption on Ionic Liquid—Modified Cu-BTC: Experimental and Simulation Study

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dc.contributorMateriales Avanzadoses_ES
dc.contributor.authorSilva, F.W.M. da-
dc.contributor.authorMagalhães, G.M.-
dc.contributor.authorJardim, Erika de Oliveira-
dc.contributor.authorSilvestre-Albero, Joaquín-
dc.contributor.authorSepúlveda-Escribano, Antonio-
dc.contributor.authorAzevedo, D.C.S. de-
dc.contributor.authorLucena, S.M.P. de-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Inorgánicaes_ES
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Materialeses_ES
dc.date.accessioned2016-09-13T10:07:29Z-
dc.date.available2016-09-13T10:07:29Z-
dc.date.issued2015-02-
dc.identifier.citationAdsorption Science & Technology. 2015, 33(2): 223-242. doi:10.1260/0263-6174.33.2.223es_ES
dc.identifier.issn0263-6174 (Print)-
dc.identifier.issn2048-4038 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/57849-
dc.description.abstractWe analyzed the adsorption of CO2 in a Cu-BTC metal-organic framework (MOF) impregnated with ionic liquids (ILs) experimentally and by molecular simulation using the Monte Carlo method. The ILs [bmim][PF6] and [bmim][Tf2N] were impregnated in concentrations of 1, 5 and 10 wt%. Monte Carlo computations showed maximum impregnation load of approximately 30 wt% and improved CO2 adsorption up to 2 bar for all the concentrations tested. Experimentally, the impregnated material was carefully characterized and CO2 isotherms were measured. High concentrations of IL solution (10 wt%) had a pronounced detrimental effect on the textural properties of Cu-BTC, whereas for low concentration (5 wt%), no improvement in CO2 adsorption was observed. Based on the experimental and simulated data, the suitability of Cu-BTC as a target MOF for IL impregnation was examined.es_ES
dc.description.sponsorshipThis work was supported by the Brazilian research agencies, CNPq and CAPES. E.O. Jardim thanks the CNPq (Brazil) for her grant.es_ES
dc.languageenges_ES
dc.publisherSAGE Publicationses_ES
dc.rights© 2015 by SAGE Publicationses_ES
dc.subjectCO2 adsorptiones_ES
dc.subjectIonic liquides_ES
dc.subjectCu-BTCes_ES
dc.subject.otherQuímica Inorgánicaes_ES
dc.titleCO2 Adsorption on Ionic Liquid—Modified Cu-BTC: Experimental and Simulation Studyes_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.peerreviewedsies_ES
dc.identifier.doi10.1260/0263-6174.33.2.223-
dc.relation.publisherversionhttp://dx.doi.org/10.1260/0263-6174.33.2.223es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccesses_ES
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