CO2 Adsorption on Ionic Liquid—Modified Cu-BTC: Experimental and Simulation Study
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Campo DC | Valor | Idioma |
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dc.contributor | Materiales Avanzados | es_ES |
dc.contributor.author | Silva, F.W.M. da | - |
dc.contributor.author | Magalhães, G.M. | - |
dc.contributor.author | Jardim, Erika de Oliveira | - |
dc.contributor.author | Silvestre-Albero, Joaquín | - |
dc.contributor.author | Sepúlveda-Escribano, Antonio | - |
dc.contributor.author | Azevedo, D.C.S. de | - |
dc.contributor.author | Lucena, S.M.P. de | - |
dc.contributor.other | Universidad de Alicante. Departamento de Química Inorgánica | es_ES |
dc.contributor.other | Universidad de Alicante. Instituto Universitario de Materiales | es_ES |
dc.date.accessioned | 2016-09-13T10:07:29Z | - |
dc.date.available | 2016-09-13T10:07:29Z | - |
dc.date.issued | 2015-02 | - |
dc.identifier.citation | Adsorption Science & Technology. 2015, 33(2): 223-242. doi:10.1260/0263-6174.33.2.223 | es_ES |
dc.identifier.issn | 0263-6174 (Print) | - |
dc.identifier.issn | 2048-4038 (Online) | - |
dc.identifier.uri | http://hdl.handle.net/10045/57849 | - |
dc.description.abstract | We analyzed the adsorption of CO2 in a Cu-BTC metal-organic framework (MOF) impregnated with ionic liquids (ILs) experimentally and by molecular simulation using the Monte Carlo method. The ILs [bmim][PF6] and [bmim][Tf2N] were impregnated in concentrations of 1, 5 and 10 wt%. Monte Carlo computations showed maximum impregnation load of approximately 30 wt% and improved CO2 adsorption up to 2 bar for all the concentrations tested. Experimentally, the impregnated material was carefully characterized and CO2 isotherms were measured. High concentrations of IL solution (10 wt%) had a pronounced detrimental effect on the textural properties of Cu-BTC, whereas for low concentration (5 wt%), no improvement in CO2 adsorption was observed. Based on the experimental and simulated data, the suitability of Cu-BTC as a target MOF for IL impregnation was examined. | es_ES |
dc.description.sponsorship | This work was supported by the Brazilian research agencies, CNPq and CAPES. E.O. Jardim thanks the CNPq (Brazil) for her grant. | es_ES |
dc.language | eng | es_ES |
dc.publisher | SAGE Publications | es_ES |
dc.rights | © 2015 by SAGE Publications | es_ES |
dc.subject | CO2 adsorption | es_ES |
dc.subject | Ionic liquid | es_ES |
dc.subject | Cu-BTC | es_ES |
dc.subject.other | Química Inorgánica | es_ES |
dc.title | CO2 Adsorption on Ionic Liquid—Modified Cu-BTC: Experimental and Simulation Study | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.peerreviewed | si | es_ES |
dc.identifier.doi | 10.1260/0263-6174.33.2.223 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1260/0263-6174.33.2.223 | es_ES |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | es_ES |
Aparece en las colecciones: | INV - LMA - Artículos de Revistas |
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2015_da-Silva_etal_AdsorptionSci&Tech_final.pdf | Versión final (acceso restringido) | 1,83 MB | Adobe PDF | Abrir Solicitar una copia |
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