Assessment of naproxen adsorption on bone char in aqueous solutions using batch and fixed-bed processes

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dc.contributorMateriales Avanzadoses_ES
dc.contributor.authorReynel-Avila, Hilda E.-
dc.contributor.authorMendoza-Castillo, Didilia I.-
dc.contributor.authorBonilla-Petriciolet, Adrian-
dc.contributor.authorSilvestre-Albero, Joaquín-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Inorgánicaes_ES
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Materialeses_ES
dc.date.accessioned2016-09-13T09:34:39Z-
dc.date.available2016-09-13T09:34:39Z-
dc.date.issued2015-09-
dc.identifier.citationJournal of Molecular Liquids. 2015, 209: 187-195. doi:10.1016/j.molliq.2015.05.013es_ES
dc.identifier.issn0167-7322 (Print)-
dc.identifier.issn1873-3166 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/57844-
dc.description.abstractAn integrated analysis of naproxen adsorption on bone char in batch and packed-bed column conditions has been performed. Kinetic, thermodynamic and breakthrough parameters have been calculated using adsorption models and artificial neural networks. Results show that naproxen removal using bone char in batch conditions is a feasible and effective process, which could involve electrostatic and non-electrostatic interactions depending mainly on pH conditions. However, the application of packed-bed column for naproxen adsorption on bone char is not effective for the treatment of diluted solutions due to the low degree of adsorbent utilization (below 4%) at tested operating conditions. The proposed mechanism for naproxen removal using bone char could include a complexation process via phosphate and naproxen, hydrogen bonding and the possibility of hydrophobic interactions via π–π electron. This study highlights the relevance of performing an integrated analysis of adsorbent effectiveness in batch and dynamic conditions to establish the best process configuration for the removal of emerging water pollutants such as pharmaceuticals.es
dc.languageenges
dc.publisherElsevieres_ES
dc.rights© 2015 Elsevier B.V.es
dc.subjectAdsorptiones
dc.subjectBone chares
dc.subjectFixed-bed columnses
dc.subjectNaproxenes
dc.subjectPharmaceuticalses
dc.subjectWater treatmentes
dc.subject.otherQuímica Inorgánicaes_ES
dc.titleAssessment of naproxen adsorption on bone char in aqueous solutions using batch and fixed-bed processeses_ES
dc.typeinfo:eu-repo/semantics/articlees
dc.peerreviewedsies
dc.identifier.doi10.1016/j.molliq.2015.05.013-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.molliq.2015.05.013es
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccesses
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