IR and electrochemical synthesis and characterization of thin films of PEDOT grown on platinum single crystal electrodes in [EMMIM]Tf2N ionic liquid

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Title: IR and electrochemical synthesis and characterization of thin films of PEDOT grown on platinum single crystal electrodes in [EMMIM]Tf2N ionic liquid
Authors: Sandoval, Andrea P. | Suárez-Herrera, Marco F. | Feliu, Juan M.
Research Group/s: Electroquímica de Superficies
Center, Department or Service: Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica
Keywords: AFM | [EMMIM]Tf2N ionic liquid | In situ IR | PEDOT | Pt single crystals
Knowledge Area: Química Física
Issue Date: 13-Mar-2015
Publisher: Beilstein-Institut
Citation: Beilstein Journal of Organic Chemistry. 2015, 11: 348-357. doi:10.3762/bjoc.11.40
Abstract: Thin films of PEDOT synthesized on platinum single electrodes in contact with the ionic liquid 1-ethyl-2,3-dimethylimidazolium triflimide ([EMMIM]Tf2N) were studied by cyclic voltammetry, chronoamperometry, infrared spectroscopy and atomic force microscopy. It was found that the polymer grows faster on Pt(111) than on Pt(110) or Pt(100) and that the redox reactions associated with the PEDOT p-doping process are much more reversible in [EMMIM]Tf2N than in acetonitrile. Finally, the ion exchange and charge carriers’ formation during the p-doping reaction of PEDOT were studied using in situ FTIR spectroscopy.
Sponsor: APS acknowledges the scholarship “Estudiantes sobresalientes de posgrado” at the “Universidad Nacional de Colombia (UNAL)” and COLCIENCIAS National Doctoral Scholarship (567). MFS acknowledges support of UNAL (Research Project 19030). JMF thanks MINECO (Spain) support through project CTQ2013-44083-P and Generalitat Valenciana (Feder) through project PROMETEOII/2014/013.
URI: http://hdl.handle.net/10045/47681
ISSN: 1860-5397
DOI: 10.3762/bjoc.11.40
Language: eng
Type: info:eu-repo/semantics/article
Rights: This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc).
Peer Review: si
Publisher version: http://dx.doi.org/10.3762/bjoc.11.40
Appears in Collections:INV - EQSUP - Artículos de Revistas

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