Electrospinning of silica sub-microtubes mats with platinum nanoparticles for NO catalytic reduction

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/44745
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dc.contributorMateriales Carbonosos y Medio Ambientees
dc.contributor.authorRuiz-Rosas, Ramiro-
dc.contributor.authorRosas, Juana M.-
dc.contributor.authorLoscertales, Ignacio G.-
dc.contributor.authorRodríguez-Mirasol, José-
dc.contributor.authorCordero, Tomás-
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Materialeses
dc.date.accessioned2015-02-12T09:14:29Z-
dc.date.available2015-02-12T09:14:29Z-
dc.date.issued2014-09-
dc.identifier.citationApplied Catalysis B: Environmental. 2014, 156-157: 15-24. doi:10.1016/j.apcatb.2014.02.047es
dc.identifier.issn0926-3373 (Print)-
dc.identifier.issn1873-3883 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/44745-
dc.description.abstractSilica sub-microtubes loaded with platinum nanoparticles have been prepared in flexible non-woven mats using co-axial electrospinning technique. A partially gelated sol made from tetraethyl orthosilicate was used as the silica precursor, and oil was used as the sacrificial template for the hollow channel generation. Platinum has been supported on the wall of the tubes just adding the metallic precursor to the sol–gel, thus obtaining the supported catalyst by one-pot method. The silica tubes have a high aspect ratio with external/internal diameters of 400/200 nm and well-dispersed platinum nanoparticles of around 2 nm. This catalyst showed a high NO conversion with very high selectivity to N2 at mild conditions in the presence of excess oxygen when using C3H6 as reducing agent. This relevant result reveals the potential of this technique to produce nanostructured catalysts onto easy to handle conformations.es
dc.description.sponsorshipThis work was supported by the Spanish Ministry of Economy and Competitiveness under CTQ2012-36408 project.es
dc.languageenges
dc.publisherElsevieres
dc.rights© 2014 Elsevier B.V.es
dc.subjectCoaxial electrospinninges
dc.subjectSilica nanotubeses
dc.subjectPlatinum nanoparticleses
dc.subjectNOx SCRes
dc.subject.otherQuímica Inorgánicaes
dc.titleElectrospinning of silica sub-microtubes mats with platinum nanoparticles for NO catalytic reductiones
dc.typeinfo:eu-repo/semantics/articlees
dc.peerreviewedsies
dc.identifier.doi10.1016/j.apcatb.2014.02.047-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.apcatb.2014.02.047es
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
Appears in Collections:INV - MCMA - Artículos de Revistas

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