Interaction of water with methanesulfonic acid on Pt single crystal electrodes

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Title: Interaction of water with methanesulfonic acid on Pt single crystal electrodes
Authors: Sandoval, Andrea P. | Suárez-Herrera, Marco F. | Climent, Victor | Feliu, Juan M.
Research Group/s: Electroquímica de Superficies
Center, Department or Service: Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica
Keywords: Methanesulfonic acid | Platinum single crystal electrodes | Cyclic voltammetry | Anion adsorption
Knowledge Area: Química Física
Issue Date: Jan-2015
Publisher: Elsevier
Citation: Electrochemistry Communications. 2015, 50: 47-50. doi:10.1016/j.elecom.2014.11.007
Abstract: The electrochemical behavior of methanesulfonic acid on platinum single crystal electrode surfaces is investigated by cyclic voltammetry and infrared spectroscopy measurements. The results are compared with the voltammetric profiles of perchloric and trifluoromethanesulfonic acids. The differences are interpreted in terms of the effect of the anion on the structure of water. No adsorbed species are detected by infrared spectroscopy.
Sponsor: APS acknowledges the scholarship “Estudiantes sobresalientes de posgrado” at the UNC and COLCIENCIAS National Doctoral Scholarship (567). MFS acknowledges the support of UNC (Research Project 19030). JMFwould like to thankGeneralitat Valenciana (Feder) through project PROMETEOII/2014/013.
URI: http://hdl.handle.net/10045/43030
ISSN: 1388-2481 (Print) | 1873-1902 (Online)
DOI: 10.1016/j.elecom.2014.11.007
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://dx.doi.org/10.1016/j.elecom.2014.11.007
Appears in Collections:INV - EQSUP - Artículos de Revistas

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