First aromatic ring acetamidation by anodic oxidation

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Title: First aromatic ring acetamidation by anodic oxidation
Authors: Barba, Fructuoso | Barba, Isidoro | Batanero, Belén
Research Group/s: Nuevos Materiales y Catalizadores (MATCAT)
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Instituto Universitario de Síntesis Orgánica
Keywords: Acetanilides | Anode | 1-(Trifluoromethyl)benzene | Acetonitrile/Bu4NBF4 | Potentiostatic conditions
Knowledge Area: Química Orgánica
Issue Date: Nov-2014
Publisher: Elsevier
Citation: Electrochemistry Communications. 2014, 48: 115-117. doi:10.1016/j.elecom.2014.08.028
Abstract: Anodic oxidation of 1-(trifluoromethyl)benzene in dry acetonitrile/Bu4NBF4 under constant potential conditions led to 2-(trifluoromethyl) acetanilide in 86% yield. Other experimental conditions, as the use of constant current or the change in the supporting electrolyte were considered.
Sponsor: This work was supported by the Spanish Ministry of Science and Education through B. Batanero I3 program the financial support.
ISSN: 1388-2481 (Print) | 1873-1902 (Online)
DOI: 10.1016/j.elecom.2014.08.028
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version:
Appears in Collections:INV - MATCAT - Artículos de Revistas

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