Influence of peroxometallic intermediaries present on polyoxometalates nanoparticles surface on the adipic acid synthesis

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Title: Influence of peroxometallic intermediaries present on polyoxometalates nanoparticles surface on the adipic acid synthesis
Authors: Alcañiz-Monge, Juan | Trautwein, Guido | Garcia-Garcia, Avelina
Research Group/s: Materiales Carbonosos y Medio Ambiente
Center, Department or Service: Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Adipic acid, Polyoxometalates, Heteropolysalts | Cyclohexene oxidation
Knowledge Area: Química Inorgánica
Issue Date: 15-Nov-2014
Publisher: Elsevier
Citation: Journal of Molecular Catalysis A: Chemical. 2014, 394: 211-216. doi:10.1016/j.molcata.2014.07.023
Abstract: The cyclohexene oxidation by hydrogen peroxide catalysed by polyoxometalates (POM) has been shown as an adequate green route for the adipic acid synthesis. In this study, it has been demonstrated that POM's salts are effective catalysts for this reaction and how peroxopolyoxometalates intermediaries are the truly responsible species of the POM's salts catalytic activity and solubility. However, the latter can be reduced by calcining the catalyst previously. Polyoxomolybdates salts generally present a higher activity than polyoxotungstenates salts. Finally, it must be remarked the positive effect exerted by the acetic acid stabilising the peroxide of hydrogen against its decomposition.
Sponsor: The authors thank the Generalitat Valenciana and FEDER (PROMETEO/2009/047), and MICINN and Plan E (CTQ2012-31762) for the financial support.
URI: http://hdl.handle.net/10045/40800
ISSN: 1381-1169 (Print) | 1873-314X (Online)
DOI: 10.1016/j.molcata.2014.07.023
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://dx.doi.org/10.1016/j.molcata.2014.07.023
Appears in Collections:INV - MCMA - Artículos de Revistas

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