Solubility, Density, Refractive Index, and Viscosity for the Polyhydric Alcohol + CsBr + H2O Ternary Systems at Different Temperatures

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Title: Solubility, Density, Refractive Index, and Viscosity for the Polyhydric Alcohol + CsBr + H2O Ternary Systems at Different Temperatures
Authors: Li, Yanjie | Li, Shu’ni | Zhai, Quanguo | Marcilla, Antonio | Jiang, Yucheng | Hu, Mancheng
Research Group/s: Procesado y Pirólisis de Polímeros
Center, Department or Service: Universidad de Alicante. Departamento de Ingeniería Química
Keywords: Solubility | Density | Refractive index | Viscosity | Polyhydric alcohol + CsBr + H2O ternary systems
Knowledge Area: Ingeniería Química
Issue Date: 10-May-2013
Publisher: American Chemical Society
Citation: Journal of Chemical & Engineering Data. 2013, 58(6): 1577-1588. doi:10.1021/je301222e
Abstract: The solubility, density, refractive index, and viscosity data for the ethylene glycol + CsBr + H2O, 1,2-propanediol + CsBr + H2O, and glycerin + CsBr + H2O ternary systems have been determined at (288.15, 298.15, and 308.15) K. In all cases, the solubility of CsBr in aqueous solutions was decreased significantly due to the presence of polyhydric alcohol. The liquid–solid equilibrium experimental data were correlated using the NRTL (nonrandom two-liquid) activity coefficient model, considering nondissociation of the dissolved salt in the liquid phase, and new interaction parameters were estimated. The mean deviations between calculated and experimental compositions were low, showing the good descriptive quality and applicability of the NRTL model. The refractive indices, densities, and viscosities for the unsaturated solutions of the three ternary systems have also been measured at three temperatures. Values for all of the properties were correlated with the salt concentrations and proportions of polyhydric alcohol in the solutions.
Sponsor: This work was supported by the National Natural Science Foundation of China (Grant No. 21171111) and the Fundamental Research Funds for the Central Universities (Grant No. GK200902011).
URI: http://hdl.handle.net/10045/40349
ISSN: 0021-9568 (Print) | 1520-5134 (Online)
DOI: 10.1021/je301222e
Language: eng
Type: info:eu-repo/semantics/article
Rights: © 2013 American Chemical Society
Peer Review: si
Publisher version: http://dx.doi.org/10.1021/je301222e
Appears in Collections:INV - GTP3 - Artículos de Investigación sobre Pirólisis Catalítica de Polímeros

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