Biodiesel production by acid catalysis with heteropolyacids supported on activated carbon fibers

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Title: Biodiesel production by acid catalysis with heteropolyacids supported on activated carbon fibers
Authors: Alcañiz-Monge, Juan | Trautwein, Guido | Marco Lozar, Juan Pablo
Research Group/s: Materiales Carbonosos y Medio Ambiente
Center, Department or Service: Universidad de Alicante. Departamento de Química Inorgánica | Universidad de Alicante. Instituto Universitario de Materiales
Keywords: Supported heteropolyacid | Palmitic acid esterification | Biodiesel | Microporosity
Knowledge Area: Química Inorgánica
Issue Date: 5-Nov-2013
Publisher: Elsevier
Citation: Applied Catalysis A: General. 2013, 468: 432-441. doi:10.1016/j.apcata.2013.09.006
Abstract: Different catalysts, based on heteropolyacids supported on activated carbon fibers, have been prepared for palmitic acid esterification reaction. The influence of the catalyst (heteropolyacid) and the support on the catalytic activity have been analyzed. The results prove that an adequate combination of both is required to achieve the most suitable catalysts. Regarding to the heteropolyacid, phosphomolybdic acid seems to be the most suitable appropriate taking into account its lowest leaching. About the support, it must show an optimum microporosity, which must be wide enough to allow the entrance and exit of the reagents and products but not too wide in order to avoid the leaching of the catalyst. In addition, both decreasing of the catalytic activity and its recovery over several cycles have been analyzed.
Sponsor: The authors thank the Generalitat Valenciana and FEDER(PROMETEO/2009/047), and MICINN and Plan E (CTQ2012-31762)for the financial support.
URI: http://hdl.handle.net/10045/40188
ISSN: 0926-860X (Print) | 1873-3875 (Online)
DOI: 10.1016/j.apcata.2013.09.006
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://dx.doi.org/10.1016/j.apcata.2013.09.006
Appears in Collections:INV - MCMA - Artículos de Revistas

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