The electrochemistry of arylated anthraquinones in room temperature ionic liquids
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Título: | The electrochemistry of arylated anthraquinones in room temperature ionic liquids |
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Autor/es: | Gomis-Berenguer, Alicia | Gomez-Mingot, Maria | García Cruz, Leticia | Thiemann, Thies | Banks, Craig E. | Montiel, Vicente | Iniesta, Jesus |
Grupo/s de investigación o GITE: | Electroquímica Aplicada y Electrocatálisis |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica |
Palabras clave: | Arylated anthraquinones | Electron transfer | Quinone | Room temperature ionic liquid | Screen printed graphite electrodes | Solvodynamic radii |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | abr-2013 |
Editor: | John Wiley & Sons |
Cita bibliográfica: | Journal of Physical Organic Chemistry. 2013, 26(4): 367-375. doi:10.1002/poc.3098 |
Resumen: | Arylated anthraquinone derivatives of different sizes and different π-basicities have been prepared, and the electrochemical behaviour of these substances has been studied on screen printed graphite electrodes in the three room temperature ionic liquids (RTILs), 1-butyl-3-methylimidazolium hexafluorophosphate ([C4MIM][PF6]), 1-hexyl-3-methylimidazolium hexafluorophosphate ([C6MIM][PF6]) and 1-octyl-3-methylimidazolium hexafluorophosphate ([C8MIM][PF6]). Half redox potentials for the first and second one electron reduction waves were identified, and the diffusion coefficient values were estimated from cyclic voltammetry measurements. The influence of the nature of the RTIL and of the substitution pattern of the anthraquinone on the solvodynamic radii were studied. A correlation of the reductive potentials with the corresponding Hammett constants of the substituents was tested. |
Patrocinador/es: | M. Gómez-Mingot thanks the University of Alicante for her fellowship. T. Thiemann thanks funding from Global Centre of Excellence on New Carbon Resources, Kyushu University, Japan. J. Iniesta acknowledges Ministerio de Educación y Ciencia MEC Spain (Project: CTQ2007-62345). |
URI: | http://hdl.handle.net/10045/38720 |
ISSN: | 0894-3230 (Print) | 1099-1395 (Online) |
DOI: | 10.1002/poc.3098 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2013 John Wiley & Sons, Ltd. |
Revisión científica: | si |
Versión del editor: | http://dx.doi.org/10.1002/poc.3098 |
Aparece en las colecciones: | INV - LEQA - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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2013_Gomis_etal_JPOC_final.pdf | Versión final (acceso restringido) | 1,78 MB | Adobe PDF | Abrir Solicitar una copia |
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