Heterogeneous catalytic homocoupling of terminal alkynes

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Title: Heterogeneous catalytic homocoupling of terminal alkynes
Authors: Alonso, Francisco | Yus, Miguel
Research Group/s: Nuevas Metodologías en Síntesis Orgánica
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica
Keywords: Alkynes | Coupling | Palladium | Copper | Heterogeneous catalysis
Knowledge Area: Química Orgánica
Date Created: 2012
Issue Date: 4-Jun-2012
Publisher: American Chemical Society
Citation: ALONSO, Francisco; YUS, Miguel. “Heterogeneous catalytic homocoupling of terminal alkynes”. ACS Catalysis. Vol. 2, No. 7 (2012). ISSN 2155-5435, pp. 1441-1451
Abstract: The homocoupling of terminal alkynes under heterogeneous catalysis is tackled in this perspective. The performance of different unsupported and supported catalysts, primarily based on palladium and copper, is analyzed from a critical point of view. This type of coupling provides the most direct access to 1,3-diynes, which can be found in nature and are very important compounds in organic synthesis.
Sponsor: The Spanish Ministerio de Ciencia e Innovación (MICINN; CTQ2007-65218, CTQ2011-24151, and Consolider Ingenio 2010-CSD2007-00006), the Generalitat Valenciana (GV; PROMETEO/2009/039), FEDER, and the Universidad de Alicante.
URI: http://hdl.handle.net/10045/23555
ISSN: 2155-5435
DOI: 10.1021/cs300195r
Language: eng
Type: info:eu-repo/semantics/article
Rights: Copyright © 2012 American Chemical Society
Peer Review: si
Publisher version: http://dx.doi.org/10.1021/cs300195r
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