Hydrosilylation of alkynes catalysed by platinum on titania

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/17285
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Title: Hydrosilylation of alkynes catalysed by platinum on titania
Authors: Alonso, Francisco | Buitrago Sierra, Robison | Moglie, Yanina | Ruiz Martínez, Javier | Sepúlveda-Escribano, Antonio | Yus, Miguel
Research Group/s: Nuevas Metodologías en Síntesis Orgánica | Materiales Avanzados
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica | Universidad de Alicante. Departamento de Química Inorgánica
Keywords: Hydrosilylation | Alkynes | Platinum | Titania | Heterogeneous catalysis
Knowledge Area: Química Orgánica | Química Inorgánica
Date Created: 2010
Issue Date: 8-Oct-2010
Publisher: Elsevier
Citation: ALONSO VALDÉS, Francisco, et al. "Hydrosilylation of alkynes catalysed by platinum on titania". Journal of Organometallic Chemistry. Vol. 696, Issue 1 (1 Jan. 2011). ISSN 0022-328X, pp. 368-372
Abstract: The heterogeneous hydrosilylation of alkynes catalysed by platinum on titania is reported. A variety of hydrosilanes react with both terminal and internal alkynes to furnish the corresponding vinyl silanes in high yields and short reaction times as well as in a regio- and stereoselective manner. The catalyst can be easily recovered and reused in several consecutive cycles.
Sponsor: This work was generously supported by the Spanish Ministerio de Ciencia e Innovación (MICINN; grant no. CTQ2007-65218, Consolider Ingenio 2010-CSD2007-00006) and the Generalitat Valenciana (GV; PROMETEO/2009/039 and PROMETEO/2009/002); University of Alicante, CAM and Union Fenosa grant (UF2007-X9159987F).
URI: http://hdl.handle.net/10045/17285
ISSN: 0022-328X (Print) | 1872-8561 (Online)
DOI: 10.1016/j.jorganchem.2010.09.068
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://dx.doi.org/10.1016/j.jorganchem.2010.09.068
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