Recent advances on the organocatalyzed enantioselective α-heterofunctionalization of carbonyl compounds

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dc.contributorDerivados de Aminoácidos y Péptidos en Síntesis Orgánicaen
dc.contributorNuevas Metodologías en Síntesis Orgánicaen
dc.contributor.authorGuillena, Gabriela-
dc.contributor.authorRamón, Diego J.-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Orgánicaen
dc.identifier.citationGUILLENA TOWNLEY, Gabriela; RAMÓN DANGLA, Diego José. "Recent advances on the organocatalyzed enantioselective α-heterofunctionalization of carbonyl compounds". Current Organic Chemistry. Vol. 15, No. 3 (2011). ISSN 1385-2728, pp. 296-327en
dc.identifier.issn1385-2728 (Print)-
dc.identifier.issn1875-5348 (Online)-
dc.description.abstractThis review covers literature on organocatalyzed enantioselective a-heterofunctionalization of carbonyl compounds from 2006 to 2009. In this review, we will consider those reactions in which a new carbon-heteroatom bond is formed using α chiral organic molecule as catalyst, excluding those processes, which involve the modification on the hybridization of a previously functionalized carbonyl compound. Using this straightforward synthetic strategy, a wide range of valuable chiral building blocks such as α-amino acids, α-amino alcohols, epoxides, 1,2-diols, α-sulfenylated, α-selenenylated and α-halogenated carbonyl derivatives can be obtained by this simple and advantageous methodology.en
dc.description.sponsorshipSpanish Ministerio Ciencia e Innovación (Consolider Ingenio 2010 CSD2007-00006, CTQ2007-65218/BQU) and the Generalitat Valenciana (Proyecto Prometeo 2009/039).en
dc.publisherBentham Science Publishersen
dc.subjectEnantioselective synthesisen
dc.subjectFunctionalized carbonyl compoundsen
dc.subjectα-amino acidsen
dc.subjectα-amino alcoholsen
dc.subjectα-halogenated carbonyl compoundsen
dc.subject.otherQuímica Orgánicaen
dc.titleRecent advances on the organocatalyzed enantioselective α-heterofunctionalization of carbonyl compoundsen
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