Recent advances on the organocatalyzed enantioselective α-heterofunctionalization of carbonyl compounds

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Title: Recent advances on the organocatalyzed enantioselective α-heterofunctionalization of carbonyl compounds
Authors: Guillena, Gabriela | Ramón, Diego J.
Research Group/s: Derivados de Aminoácidos y Péptidos en Síntesis Orgánica | Nuevas Metodologías en Síntesis Orgánica
Center, Department or Service: Universidad de Alicante. Departamento de Química Orgánica
Keywords: Enantioselective synthesis | Organocatalysis | Functionalized carbonyl compounds | α-amino acids | α-amino alcohols | α-halogenated carbonyl compounds
Knowledge Area: Química Orgánica
Issue Date: Feb-2011
Publisher: Bentham Science Publishers
Citation: GUILLENA TOWNLEY, Gabriela; RAMÓN DANGLA, Diego José. "Recent advances on the organocatalyzed enantioselective α-heterofunctionalization of carbonyl compounds". Current Organic Chemistry. Vol. 15, No. 3 (2011). ISSN 1385-2728, pp. 296-327
Abstract: This review covers literature on organocatalyzed enantioselective a-heterofunctionalization of carbonyl compounds from 2006 to 2009. In this review, we will consider those reactions in which a new carbon-heteroatom bond is formed using α chiral organic molecule as catalyst, excluding those processes, which involve the modification on the hybridization of a previously functionalized carbonyl compound. Using this straightforward synthetic strategy, a wide range of valuable chiral building blocks such as α-amino acids, α-amino alcohols, epoxides, 1,2-diols, α-sulfenylated, α-selenenylated and α-halogenated carbonyl derivatives can be obtained by this simple and advantageous methodology.
Sponsor: Spanish Ministerio Ciencia e Innovación (Consolider Ingenio 2010 CSD2007-00006, CTQ2007-65218/BQU) and the Generalitat Valenciana (Proyecto Prometeo 2009/039).
URI: http://hdl.handle.net/10045/16905
ISSN: 1385-2728 (Print) | 1875-5348 (Online)
Language: eng
Type: info:eu-repo/semantics/article
Peer Review: si
Publisher version: http://www.benthamscience.com/coc/index.htm
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