Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/14594
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dc.contributorNuevas Metodologías en Síntesis Orgánicaen
dc.contributor.authorNador, Fabiana-
dc.contributor.authorMoglie, Yanina-
dc.contributor.authorVitale, Cristian-
dc.contributor.authorYus, Miguel-
dc.contributor.authorAlonso, Francisco-
dc.contributor.authorRadivoy, Gabriel-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Orgánicaen
dc.contributor.otherUniversidad Nacional del Sur (Bahía Blanca, Argentina). Departamento de Químicaen
dc.date.accessioned2010-09-27T09:11:53Z-
dc.date.available2010-09-27T09:11:53Z-
dc.date.created2010-
dc.date.issued2010-04-10-
dc.identifier.citationNADOR, Fabiana, et al. "Reduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticles". Tetrahedron. Vol. 66, No. 24 (12 June 2010). ISSN 0040-4020, pp. 4318-4325en
dc.identifier.issn0040-4020 (Print)-
dc.identifier.issn1464-5416 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/14594-
dc.description.abstractA new methodology for the partial reduction of polycyclic aromatic and heteroaromatic hydrocarbons under mild reaction conditions is presented, the process being a reasonable alternative to the catalytic hydrogenation or the Birch reaction. The reduction protocol described is based on the use of cobalt or manganese nanoparticles generated in situ in a simple and economic way, by reduction of commercially available CoCl2·6H2O or MnCl2·2H2O in the presence of lithium sand and the corresponding PAH, acting itself as an electron carrier. The use of a deuterium-oxide-containing cobalt(II) salt allows the simple preparation of deuterium labeled products. The regiochemistry and degree of reduction in the case of 1-substituted naphthalene derivatives markedly depends on the nature of the metal-NPs used.en
dc.description.sponsorshipCONICET (Consejo Nacional de Investigaciones Científicas y Técnicas, Project PIP 5104) and SGCyT-UNS (Secretaría General de Ciencia y Tecnología-Universidad Nacional del Sur, Project 24/Q026) from Argentina for financial support. Ministerio de Educación y Ciencia (MEC; grant no. CTQ2007-65218 and Consolider Ingenio 2010-CSD2007-00006) and the Generalitat Valenciana (grant no. PROMETEO/2009/039).en
dc.languageengen
dc.publisherElsevieren
dc.subjectCobalten
dc.subjectManganeseen
dc.subjectNanoparticlesen
dc.subjectReductionen
dc.subjectPolycyclic aromatic hydrocarbonsen
dc.subject.otherQuímica Orgánicaen
dc.titleReduction of polycyclic aromatic hydrocarbons promoted by cobalt or manganese nanoparticlesen
dc.typeinfo:eu-repo/semantics/articleen
dc.peerreviewedsien
dc.identifier.doi10.1016/j.tet.2010.04.026-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.tet.2010.04.026en
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccess-
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