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Heterogenization of a Chiral Molecular Catalyst on a Carbon Support using Tryptophan as Anchor Molecule

Please use this identifier to cite or link to this item: http://hdl.handle.net/10045/112082
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dc.contributorMateriales Carbonosos y Medio Ambientees_ES
dc.contributor.authorRufete Beneite, Mónica-
dc.contributor.authorRomán-Martínez, M. Carmen-
dc.contributor.otherUniversidad de Alicante. Departamento de Química Inorgánicaes_ES
dc.contributor.otherUniversidad de Alicante. Instituto Universitario de Materialeses_ES
dc.date.accessioned2021-01-19T08:44:50Z-
dc.date.available2021-01-19T08:44:50Z-
dc.date.issued2021-01-22-
dc.identifier.citationEuropean Journal of Inorganic Chemistry. 2021, 3: 223-225. https://doi.org/10.1002/ejic.202000843es_ES
dc.identifier.issn1434-1948 (Print)-
dc.identifier.issn1099-0682 (Online)-
dc.identifier.urihttp://hdl.handle.net/10045/112082-
dc.description.abstractThe (R,R)‐RhDuphos chiral catalyst has been heterogenized on the surface of a carbon material with the aid of L‐tryptophan (Trp) as anchor molecule. Trp is effectively adsorbed on the carbon surface through its arene unit and is able to coordinate Rh by means of the carbonyl and amine functional groups. The chiral hybrid catalysts prepared are very active for the asymmetric hydrogenation of 2‐methyl‐acetamidoacrylate with an acceptable enantioselectivity. Besides, when prepared with a high Tpr/Rh ratio they have shown to be stable and reusable.es_ES
dc.description.sponsorshipThe authors thank funding to the Spanish Ministry of Science, Innovation and Universities, Generalitat Valenciana and FEDER, projects of reference RTI2018-095291-B-I00 and PROMETEO/2018/076 and also University of Alicante (, project VIGROB-136).es_ES
dc.languageenges_ES
dc.publisherWiley-VCH GmbHes_ES
dc.rights© 2020 Wiley‐VCH GmbHes_ES
dc.subject(R,R)-RhDuphoses_ES
dc.subjectCarbon materiales_ES
dc.subjectL-tryptophanes_ES
dc.subjectHeterogenizationes_ES
dc.subjectAsymmetric hydrogenationes_ES
dc.subject.otherQuímica Inorgánicaes_ES
dc.titleHeterogenization of a Chiral Molecular Catalyst on a Carbon Support using Tryptophan as Anchor Moleculees_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.peerreviewedsies_ES
dc.identifier.doi10.1002/ejic.202000843-
dc.relation.publisherversionhttps://doi.org/10.1002/ejic.202000843es_ES
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-095291-B-I00-
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