Isotopic study of the La0.7Ag0.3MnOδ≤3 perovskite-catalyzed soot oxidation in presence of NO
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Título: | Isotopic study of the La0.7Ag0.3MnOδ≤3 perovskite-catalyzed soot oxidation in presence of NO |
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Autor/es: | Urán, Laura | Gallego, Jaime | Bailón-García, Esther | Bueno López, Agustín | Santamaría, Alexander |
Grupo/s de investigación o GITE: | Materiales Carbonosos y Medio Ambiente |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Inorgánica |
Palabras clave: | La0.7Ag0.3MnOδ≤3 perovskite-like catalyst | Isotopic oxygen exchange | Soot oxidation | NOx | Metallic silver sites |
Área/s de conocimiento: | Química Inorgánica |
Fecha de publicación: | 5-jun-2020 |
Editor: | Elsevier |
Cita bibliográfica: | Applied Catalysis A: General. 2020, 599: 117611. doi:10.1016/j.apcata.2020.117611 |
Resumen: | Soot oxidation process over La0.7Ag0.3MnOδ≤3 (LAM) and LaMnO3 (LM) catalysts was studied through 18O2 isotopic labelling experiments in the presence and absence of NO, using catalyst-soot mixtures under loose contact conditions. Isotopic exchange experiments evidenced that silver-particles enhanced oxygen exchange capacity, explained by the increase of oxygen active sites formed due to the charge compensation mechanism in the perovskite-like structure due to silver incorporation, and metallic-silver-segregated on catalytic surface. This enhanced oxygen exchange ability leads to the improvement of the catalytic soot oxidation capacity. The elucidated reaction-pathway indicated that catalyst oxygen is transferred to soot, and then gas-phase-oxygen occupies the vacancies created. Furthermore, 16-oxygen species coming from catalyst play an important role in the formation of NOx-adsorbed species that lead to NO2 formation, which assists soot oxidation. The desorption of NO2 was favored with Ag-particles presence because it promoted the formation of less thermally stable adsorbed NOx species. |
Patrocinador/es: | The authors want to thank the University of Antioquia for the financial support received through the CODI project No 2015-7828. L.U. thanks the Colombian Administrative Department of Science, Technology and Innovation (COLCIENCIAS), for the Ph.D. Scholarship granted; to the ENLAZA-MUNDOS program from Mayor’s office in Medellín, for the partial-support to an international internship; and to Professor Agustín Bueno from MCMA research group at materials institute of University of Alicante (IUMA), for the international internship. |
URI: | http://hdl.handle.net/10045/106858 |
ISSN: | 0926-860X (Print) | 1873-3875 (Online) |
DOI: | 10.1016/j.apcata.2020.117611 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © 2020 Elsevier B.V. |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1016/j.apcata.2020.117611 |
Aparece en las colecciones: | INV - MCMA - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
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Uran_etal_2020_ApplCat_final.pdf | Versión final (acceso restringido) | 2,23 MB | Adobe PDF | Abrir Solicitar una copia |
Uran_etal_2020_ApplCat_accepted.pdf | Accepted Manuscript (acceso abierto) | 3,43 MB | Adobe PDF | Abrir Vista previa |
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